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膜分离 5

Cu(In 4

绿色化工 4

薄膜润滑 4

Ga)Se₂ 3

反渗透 3

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双极板 2

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固体氧化物燃料电池 2

气体分离 2

水处理 2

水安全 2

纳滤 2

耐氯性 2

聚偏氟乙烯 2

聚酰胺 2

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Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for

《环境科学与工程前沿（英文）》 2022年第16卷第4期 doi: 10.1007/s11783-021-1474-7

摘要：

• PA layer properties tune the primary nanochannels in MIL-101(Cr) TFN NF membranes.

关键词： Porous metal organic framework Thin-film nanocomposite membrane Primary selective nanochannels Nanofiltration Endocrine disrupting compounds

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mesoporous silica nanoparticle with 4-triethoxysilylaniline to enhance seawater desalination properties of thin-filmnanocomposite reverse osmosis membranes

Jian Wang, Qun Wang, Xueli Gao, Xinxia Tian, Yangyang Wei, Zhen Cao, Chungang Guo, Huifeng Zhang, Zhun Ma, Yushan Zhang

《环境科学与工程前沿（英文）》 2020年第14卷第1期 doi: 10.1007/s11783-019-1185-5

摘要： Mesoporous silica nanoparticle was modified with 4-triethoxysilylaniline. AMSN-based TFN-RO membranes were prepared for seawater desalination. Water transport capability of the AMSN was limited by polyamide. Polyamide still plays a key role in permeability of the TFN RO membranes. Mesoporous silica nanoparticles (MSN), with higher water permeability than NaA zeolite, were used to fabricate thin-film nanocomposite (TFN) reverse osmosis (RO) membranes. However, only aminoalkyl-modified MSN and low-pressure (less than 2.1 MPa) RO membrane were investigated. In this study, aminophenyl-modified MSN (AMSN) were synthesized and used to fabricate high-pressure (5.52 MPa) RO membranes. With the increasing of AMSN dosage, the crosslinking degree of the aromatic polyamide decreased, while the hydrophilicity of the membranes increased. The membrane morphology was maintained to show a ridge-and-valley structure, with only a slight increase in membrane surface roughness. At the optimum conditions (AMSN dosage of 0.25 g/L), when compared with the pure polyamide RO membrane, the water flux of the TFN RO membrane (55.67 L/m2/h) was increased by about 21.6%, while NaCl rejection (98.97%) was slightly decreased by only 0.29%. However, the water flux of the membranes was much lower than expected. We considered that the enhancement of RO membrane permeability is attributed to the reduction of the effective thickness of the PA layer.

关键词： Thin film nanocomposite membrane Reverse osmosis Seawater desalination Aminophenyl-functionalized mesoporous silica nanoparticles

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Effect of adding a smart potassium ion-responsive copolymer into polysulfone support membrane on theperformance of thin-film composite nanofiltration membrane

Meibo He, Zhuang Liu, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

《化学科学与工程前沿（英文）》 2019年第13卷第2期页码 400-414 doi: 10.1007/s11705-018-1757-0

摘要： Thin-film composite (TFC) nanofiltration (NF) membranes were fabricated via the interfacial polymerization of piperazine (PIP) and 1,3,5-benzenetricarbonyl trichloride on polysulfone (PSf) support membranes blended with K -responsive poly( -isopropylacryamide-co-acryloylamidobenzo-15-crown-5) (P(NIPAM-co-AAB C )). Membranes were characterized by attenuated total reflection Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, atomic force microscope, scanning electron microscope, contact angle, and filtration tests. The results showed that: (1) Under K -free conditions, the blended P(NIPAM-co-AAB C )/PSf supports had porous and hydrophilic surfaces, thereby producing NF membranes with smooth surfaces and low MgSO rejections; (2) With K in the PIP solution, the surface roughness and water permeability of the resultant NF membrane were increased due to the K -induced transition of low-content P(NIPAM-co-AAB C ) from hydrophilic to hydrophobic; (3) After a curing treatment at 95 °C, the improved NF membrane achieved an even higher pure water permeability of 10.97 L·m ·h ·bar under 200 psi. Overall, this study provides a novel method to improve the performance of NF membranes and helps understand the influence of supports on TFC membranes.

关键词： nanofiltration interfacial polymerization support membrane potassium ion-responsive thin-film composite

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Recent development and application of thin-film thermoelectric cooler

Yuedong Yu, Wei Zhu, Xixia Kong, Yaling Wang, Pengcheng Zhu, Yuan Deng

《化学科学与工程前沿（英文）》 2020年第14卷第4期页码 492-503 doi: 10.1007/s11705-019-1829-9

摘要： Recently, the performance and fabrication of thin-film thermoelectric materials have been largely enhanced. Based on this enhancement, the thin-film thermoelectric cooler (TEC) is becoming a research hot topic, due to its high cooling flux and microchip level size. To fulfill a thin-film TEC, interfacial problems are unavoidable, as they may largely reduce the properties of a thin-film TEC. Moreover, the architecture of a thin-film TEC should also be properly designed. In this review, we introduced the enhancement of thermoelectric properties of (Bi,Sb) (Te,Se) solid solution materials by chemical vapor deposition, physical vapor deposition and electrodeposition. Then, the interfacial problems, including contact resistance, interfacial diffusion and thermal contact resistance, were discussed. Furthermore, the design, fabrication, as well as the performance of thin-film TECs were summarized.

关键词： thin-film thermoelectric cooler interfaces cooling flux TE device fabrication

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基于Cu(In,Ga)Se₂ 低成本薄膜的光伏技术的进展

Powalla Michael,Paetel Stefan,Hariskos Dimitrios,Wuerz Roland,Kessler Friedrich,Lechner Peter,Wischmann Wiltraud,Magorian Friedlmeier Theresa

《工程（英文）》 2017年第3卷第4期页码 445-451 doi: 10.1016/J.ENG.2017.04.015

摘要：

本文讨论了基于Cu(In,Ga)Se ₂ (CIGS) 复合薄膜半导体材料的光伏（PV）技术。主要内容包括CIGS技术与传统的晶体硅技术的总体比较、CIGS 技术基础、一种柔性CIGS 电池产品破世界纪录的转化效率，以及在生产、应用和稳定性方面的突出表现和良好的发展前景。CIGS 技术极具潜力，若能实现大规模量产，将成为所有光伏清洁发电技术中成本最低的一种技术。

关键词：薄膜光伏太阳能柔性 Cu(In Ga)Se₂

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Thin-film composite forward osmosis membranes with substrate layer composed of polysulfone blended with

Baicang Liu,Chen Chen,Pingju Zhao,Tong Li,Caihong Liu,Qingyuan Wang,Yongsheng Chen,John Crittenden

《化学科学与工程前沿（英文）》 2016年第10卷第4期页码 562-574 doi: 10.1007/s11705-016-1588-9

摘要： To advance commercial application of forward osmosis (FO), we investigated the effects of two additives on the performance of polysulfone (PSf) based FO membranes: one is poly(ethylene glycol) (PEG), and another is PSf grafted with PEG methyl ether methacrylate (PSf-g-PEGMA). PSf blended with PEG or PSf-g-PEGMA was used to form a substrate layer, and then polyamide was formed on a support layer by interfacial polymerization. In this study, NaCl (1 mol?L ) and deionized water were used as the draw solution and the feed solution, respectively. With the increase of PEG content from 0 to 15 wt-%, FO water flux declined by 23.4% to 59.3% compared to a PSf TFC FO membrane. With the increase of PSf-g-PEGMA from 0 to 15 wt-%, the membrane flux showed almost no change at first and then declined by about 52.0% and 50.4%. The PSf with 5 wt-% PSf-g-PEGMA FO membrane showed a higher pure water flux of 8.74 L?m ?h than the commercial HTI membranes (6–8 L?m ?h ) under the FO mode. Our study suggests that hydrophobic interface is very important for the formation of polyamide, and a small amount of PSf-g-PEGMA can maintain a good condition for the formation of polyamide and reduce internal concentration polarization.

关键词： thin-film composite forward osmosis amphiphilic copolymer interfacial polymerization poly(ethylene glycol)

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Fabrication of Si-based three-dimensional microbatteries: A review

Chuang YUE, Jing LI, Liwei LIN

《机械工程前沿（英文）》 2017年第12卷第4期页码 459-476 doi: 10.1007/s11465-017-0462-x

摘要：

High-performance, Si-based three-dimensional (3D) microbattery systems for powering micro/nano-electromechanical systems and lab-on-chip smart electronic devices have attracted increasing research attention. These systems are characterized by compatible fabrication and integratibility resulting from the silicon-based technologies used in their production. The use of support substrates, electrodes or current collectors, electrolytes, and even batteries used in 3D layouts has become increasingly important in fabricating microbatteries with high energy, high power density, and wide-ranging applications. In this review, Si-based 3D microbatteries and related fabrication technologies, especially the production of micro-lithium ion batteries, are reviewed and discussed in detail in order to provide guidance for the design and fabrication.

关键词： three-dimensional (3D) wafer-scale Si-based anode micro-LIBs thin-film deposition

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Surface-tailoring chlorine resistant materials and strategies for polyamide thin film composite reverse

《化学科学与工程前沿（英文）》 2022年第16卷第5期页码 564-591 doi: 10.1007/s11705-021-2109-z

摘要： Polyamide thin film composite membranes have dominated current reverse osmosis market on account of their excellent separation performances compared to the integrally skinned counterparts. Despite their very promising separation performance, chlorine-induced degradation resulted from the susceptibility of polyamide toward chlorine attack has been regarded as the Achilles’s heel of polyamide thin film composite. The free chlorine species present during chlorine treatment can impair membrane performance through chlorination and depolymerization of the polyamide selective layer. From material point of view, a chemically stable membrane is crucial for the sustainable application of membrane separation process as it warrants a longer membrane lifespan and reduces the cost involved in membrane replacement. Various strategies, particularly those involved membrane material optimization and surface modifications, have been established to address this issue. This review discusses membrane degradation by free chlorine attack and its correlation with the surface chemistry of polyamide. The advancement in the development of chlorine resistant polyamide thin film composite membranes is reviewed based on the state-of-the-art surface modifications and tailoring approaches which include the in situ and post-fabrication membrane modifications using a broad range of functional materials. The challenges and future directions in this field are also highlighted.

关键词： reverse osmosis polyamide thin film composite membranes chlorine resistance surface modification

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Thin-liquid-film evaporation at contact line

Hao WANG, Zhenai PAN, Zhao CHEN

《能源前沿（英文）》 2009年第3卷第2期页码 141-151 doi: 10.1007/s11708-009-0020-2

摘要： When a liquid wets a solid wall, the extended meniscus near the contact line may be divided into three regions: a nonevaporating region, where the liquid is adsorbed on the wall; a transition region or thin-film region, where effects of long-range molecular forces (disjoining pressure) are felt; and an intrinsic meniscus region, where capillary forces dominate. The thin liquid film, with thickness from nanometers up to micrometers, covering the transition region and part of intrinsic meniscus, is gaining interest due to its high heat transfer rates. In this paper, a review was made of the researches on thin-liquid-film evaporation. The major characteristics of thin film, thin-film modeling based on continuum theory, simulations based on molecular dynamics, and thin-film profile and temperature measurements were summarized.

关键词： meniscus thin film contact line disjoining pressure evaporation

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薄膜润滑研究的回顾与展望

雒建斌,张朝辉,温诗铸

《中国工程科学》 2003年第5卷第7期页码 84-89

摘要：

薄膜润滑是20世纪90年代以来广泛研究的新型润滑状态。它是界于弹流润滑和边界润滑之间的一种过渡润滑状态，有着自己独特的润滑规律。文章回顾了薄膜润滑的研究历史，包括薄膜润滑概念的提出、测试技术的发展、薄膜润滑的膜厚特性、润滑机理探索以及计算理论等方面的研究成果与主要进展。

关键词：薄膜润滑有序膜膜厚测量微结构

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反渗透和纳滤膜的研制与应用

张奇峰,李胜海,王屯钰,李磊,张所波

《中国工程科学》 2014年第16卷第12期页码 17-23

摘要：

本文介绍了基于联苯多元酰氯单体的聚酰胺反渗透和纳滤复合膜材料体系。通过系统研究聚合物的官能团含量、取代基位置等因素对反渗透复合膜性能的影响，揭示了有价值的实验规律： a.通过调节酰氯单体的官能度，可以实现对反渗透复合膜的性质，包括表面形貌、表面化学组成、表面荷电性质的调控，从而实现对复合膜分离性能及抗污染性能的调控；b.可以利用联苯多元酰氯单体制备得到纳滤复合膜，所得纳滤膜的孔径和荷电性质可以通过调节制膜工艺实现调控。这些结果，为进一步优化制膜工艺，提供可供产业化生产的新型反渗透和纳滤复合膜制备技术奠定了基础。

关键词：反渗透膜纳滤膜联苯多元酰氯

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碱金属掺杂对CIGS 薄膜及电池器件的影响

孙云,林舒平,李伟,程世清,张运祥,刘一鸣,刘玮

《工程（英文）》 2017年第3卷第4期页码 452-459 doi: 10.1016/J.ENG.2017.04.020

摘要：

本文总结了Cu(In, Ga)Se₂ (CIGS) 电池中掺杂碱金属的发展历史和一些重要成果，综述了碱金属掺杂方式对CIGS 吸收层及器件性能的影响。通过分析由(NaF+KF)-PDT 导致的CIGS 表面结构及电学性能的改变，我们提出并解释了如下几个问题：①在低温沉积CIGS 薄膜过程中，Na 促进了CuInSe₂的优先形成，排挤Ga 向Mo 衬底扩散，造成CIGS 薄膜的分层现象；② Na 原子钝化CIGS 晶界及表面缺陷从而提高空穴载流子浓度的相关机制；③过渡层减薄提高了短路电流（J_SC）而不产生开路电压（V_OC）损失，这不仅归因于化学浴沉积初期过渡层较好的包覆性，还在于受主缺陷 $V Cu −$ 转型为施主缺陷 $Cd Cu +$ 时密度的增加，强化了同质浅埋结；④ (NaF+KF)-PDT 使CIGS 吸收层表面价带降低，进一步抑制了CIGS 吸收层和过渡层界面的复合，是提高电池开路电压与填充因子的重要原因。

关键词：碱金属 Cu(In Ga)Se₂ 薄膜太阳能电池 PDT

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Ni-Ti-Cu-V四元薄膜库中微观结构和相变的组合合成和高通量表征 Article

Naila M. Al Hasan, Huilong Hou, Suchismita Sarkar, Sigurd Thienhaus, Apurva Mehta, Alfred Ludwig, Ichiro Takeuchi

《工程（英文）》 2020年第6卷第6期页码 637-643 doi: 10.1016/j.eng.2020.05.003

摘要：

过去70年来，基于Ni-Ti的形状记忆合金（shape memory alloy, SMA）已得到广泛使用，但是提高其功能稳定性仍然是实现更稳健和更高级应用的关键。SMA因其能够通过可逆的马氏体转变来保持加工后的形状而得名，它对成分的变化非常敏感。因此，用三元和四元元素合金化来微调SMA 的晶格参数和热滞，成为材料研究中的一个难题。组合材料科学允许从多种表征技术中简化合成过程和数据管理。本研究采用磁控溅射的方法，在热氧化的硅晶片上制备了具有成分分布的Ni-TiCu-V薄膜库。使用高通量波长色散光谱、同步加速器X射线衍射和温度相关的电阻，测量研究并确定了成分相关的相变温度和微观结构。在材料库的177种成分中，有32种成分具有形状记忆效应，其中5种成分具有零或接近零的热滞效应。应用中，这些合金成分在给定工作温度范围内提供了选择的灵活性。结合薄膜库的局部微观结构和组成，讨论了四元体系的相图和功能特性的相关性。

关键词： Ni–Ti–Cu–V合金组合材料科学四元合金形状记忆合金薄膜库弹性冷却热弹性冷却相变高通量表征属性映射机器学习

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对二氧化碳具有选择性的聚环氧乙烷基薄膜的发展——从实验室到中试规模

Brinkmann Torsten,Lillepärg Jelena,Notzke Heiko,Pohlmann Jan,Shishatskiy Sergey,Wind Jan,Wolff Thorsten

《工程（英文）》 2017年第3卷第4期页码 485-493 doi: 10.1016/J.ENG.2017.04.004

摘要：

气体膜分离法是从气流中分离二氧化碳（CO₂）的最有前途的技术之一。例如，采用该技术对燃烧过程中的烟气进行处理，以达到CO₂ 捕集和封存的目的。聚环氧乙烷嵌段共聚物能够很好地应用于膜分离技术，如Pebax® 或PolyActive™。本文采用PolyActive™ 作为复合薄膜的选择层。在环境温度下，当CO₂/N₂ 选择性超过55 时，这种薄膜的CO₂渗透率高达4 m³(STP)·m⁻²·h⁻¹·bar⁻¹（注：1bar=10⁵ Pa）。这种薄膜可以按照中试规模进行生产放大，而且可以设计成不同的平面膜组件。采用单一气体渗透数据作为唯一的实验输入而开发出的仿真工具可以准确预测这种膜组件的性能。在不同的中试研究中，我们利用烟气和沼气作为原料气流，反复检测这些膜和膜组件的性能。PolyActive™ 在检测中显示出了稳定的分离性能，表明PolyActive™ 非常适用于作为膜材料进行工业规模气体处理。

关键词：气体渗透薄膜复合膜 CO₂分离 CCS 沼气处理膜组件

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Fabrication of titania thin film with composite nanostructure and its ability to photodegrade rhodamine

ZHANG Gaojie, WU Jinming, LIU Shaoguang, YAN Mi

《化学科学与工程前沿（英文）》 2008年第2卷第1期页码 44-48 doi: 10.1007/s11705-008-0001-8

摘要： A titania nanorod film was synthesized by direct oxidation of metallic Ti with hydrogen peroxide solution under a low temperature. Titania nanoparticles were then filled into the gaps among the nanorods through an infiltration sol-gel procedure to form a composite titania film with an ordered nanostructure. X-ray diffraction spectra indicate that the composite film was a mixture of anatase and rutile while the titania film obtained by only using a sol-gel procedure was pure anatase. Field emission scanning electron microscopy observations show that titania nanoparticles were embedded into the titania nanorod film. Photoluminescence spectra suggest the enhanced separation of electron and hole pairs for the obtained composite titania film over the corresponding titania nanorod film. The composite titania film exhibited improved ability to photodegrade rhodamine B in water compared with the titania nanorod film. The apparent photodegradation rate constant, fitting a pseudo-first-order, was 3 times of that obtained by the sol-gel derived titania film at the same weight. The improved photocatalytic activity for the composite titania film could be attributed to the enhanced separation of electron and hole pairs due to the embedding of the titania nanoparticles within the titania nanorods.

关键词： constant weight apparent photodegradation hydrogen nanorod

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标题作者时间类型操作

Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for

期刊论文

mesoporous silica nanoparticle with 4-triethoxysilylaniline to enhance seawater desalination properties of thin-filmnanocomposite reverse osmosis membranes

Jian Wang, Qun Wang, Xueli Gao, Xinxia Tian, Yangyang Wei, Zhen Cao, Chungang Guo, Huifeng Zhang, Zhun Ma, Yushan Zhang

期刊论文

Effect of adding a smart potassium ion-responsive copolymer into polysulfone support membrane on theperformance of thin-film composite nanofiltration membrane

Meibo He, Zhuang Liu, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

期刊论文

Recent development and application of thin-film thermoelectric cooler

Yuedong Yu, Wei Zhu, Xixia Kong, Yaling Wang, Pengcheng Zhu, Yuan Deng

期刊论文

基于Cu(In,Ga)Se₂ 低成本薄膜的光伏技术的进展

Powalla Michael,Paetel Stefan,Hariskos Dimitrios,Wuerz Roland,Kessler Friedrich,Lechner Peter,Wischmann Wiltraud,Magorian Friedlmeier Theresa

期刊论文

Thin-film composite forward osmosis membranes with substrate layer composed of polysulfone blended with

Baicang Liu,Chen Chen,Pingju Zhao,Tong Li,Caihong Liu,Qingyuan Wang,Yongsheng Chen,John Crittenden

期刊论文

Fabrication of Si-based three-dimensional microbatteries: A review